Numéro |
Sci. Tech. Energ. Transition
Volume 79, 2024
Synthesis and characterisation of porous materials for clean energy applications
|
|
---|---|---|
Numéro d'article | 31 | |
Nombre de pages | 15 | |
DOI | https://doi.org/10.2516/stet/2024023 | |
Publié en ligne | 6 juin 2024 |
Regular Article
Characterizing microstructures with representative tortuosities
1
CERVO Brain Research Center, Université Laval, 2601 Chemin de la Canardière, Québec, QC G1J 2G3, Canada
2
Univ. Lyon, UJM-Saint-Etienne, CNRS, Institute of Optics Graduate School, Laboratoire Hubert Curien UMR5516, 42023 St-Etienne, France
3
Department of Psychiatry and Neuroscience, Université Laval, Québec, QC, Canada
4
IFP Energies nouvelles, Rond-point de l’échangeur de Solaize, BP 3, 69360 Solaize, France
5
Centre d’optique, photonique et laser, Université Laval, 2375 rue de la Terrasse, Québec, QC, G1V 0A6, Canada
6
Joint International Research Unit between Université Laval, Québec, QC, Canada and Centre for Psychiatric Neuroscience, Department of Psychiatry, Lausanne University Hospital and University of Lausanne, Prilly, Switzerland
* Corresponding author: johan.chaniot.1@ulaval.ca
Received:
24
October
2023
Accepted:
29
March
2024
This paper addresses the numerical characterization of microstructures by the concept of tortuosity. After a brief review of geometric tortuosities, some definitions are considered for a benchmarking analysis. The focus is on the M-tortuosity definition, which is revised by expliciting the link to percolation theory, among other things. This operator fits with the analysis of real samples of materials whatever their complexity. A contribution of this paper is a new formulation of the M-tortuosity, making it generic to many situations. Additionally, the comparison of the various tortuosimetric descriptors, state-of-the-art definitions and M-tortuosity, is proposed by considering several scenarios thanks to stochastic multi-scale models of complex materials. The relationships with porosity, morphological heterogeneity and structural anisotropy are investigated. The results highlight the similarities and differences between the descriptors while attesting that the M-tortuosity is equivalent to the state-of-the-art definitions, for a potential use in diffusion and conductivity analyses. Moreover, the M-tortuosity handles correctly situations where state-of the-art algorithms fail. The anisotropic case highlights some limitations of the state-of-the-art definitions behaving differently according to the given propagation direction. In the case of unknown propagation and irregular piece of materials, the M-tortuosity provides a unique tortuosity value representative of the whole microstructure while detecting the anisotropy. These operators are freely available within the plug im! platform.
Key words: Microstructure / Materials science / Porous network / Morphological analysis / Mathematical morphology / Topology / Connectivity / Tortuosity / Geodesic distance transform / Percolation / Boolean model / Anisotropy / Heterogeneity
© The Author(s), published by EDP Sciences, 2024
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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